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ZLD Industrial Applications

Zero liquid discharge is deployed across multiple sectors driven by different regulatory, environmental, and operational imperatives. This page covers the principal applications and the engineering challenges specific to each.

ZLD by Industry

Textile & Dyeing — India & South Asia

The textile sector is the most significant ZLD market globally. CPCB mandates in India’s 17 critically polluted industrial clusters require zero effluent discharge from dyeing and printing units. Key challenges: reactive and disperse dyes raise colour and COD; salt (NaCl) used in dyeing at 50–100 g/L creates very high TDS feed; TDS varies widely with production schedule.

  • Typical feed: TDS 5,000–25,000 mg/L; COD 1,000–8,000 mg/L; colour 500–5,000 Pt-Co units
  • Pre-treatment: biological treatment (MBR) + coagulation + multimedia filter
  • Concentration train: two-pass RO (65% recovery) → MVR evaporator → forced-circulation crystalliser
  • Salt product: NaCl recycle to dyeing process (reduces procurement cost by 40–60%)
  • Regulatory status: CPCB mandated; state pollution control boards issuing closure notices for non-compliance

Power Generation — FGD Blowdown

Flue gas desulphurisation (FGD) systems scrub SO&sub2; from coal and oil combustion with limestone slurry. The resulting FGD blowdown wastewater contains 20,000–60,000 mg/L TDS with high sulphate, chloride, selenium, mercury, and arsenic. The US EPA ELG rule (2020) and EU IED BAT Conclusions require near-zero liquid discharge from FGD systems.

  • Typical challenges: gypsum (CaSO&sub4;) scaling; selenium at 50–200 µg/L requiring biological selenium removal; mercury speciation
  • Process train: biological selenium/mercury removal → softening → seeded slurry evaporator → crystalliser
  • Crystal product: mixed gypsum/NaCl waste requiring licensed disposal
  • Steam integration: waste steam from steam turbine used as MEE heating medium significantly reduces operating requirement

Pharmaceutical — API Containment

Pharmaceutical manufacturing sites face dual ZLD drivers: API containment obligations (EMA, US FDA guidance) prevent discharge of trace pharmaceuticals; and several sites in water-stressed regions are required to achieve water neutrality. Active pharmaceutical ingredients (APIs) at ng/L to µg/L levels must be destroyed before any discharge.

  • API destruction: AOP (Fenton or UV/H&sub2;O&sub2;) or wet air oxidation ahead of ZLD train
  • Membrane stages must handle solvents (acetonitrile, methanol, ethanol) — standard RO membranes not suitable; specialist solvent-resistant membranes required
  • Typical train: distillation (solvent recovery) → biological treatment → AOP → RO → evaporation
  • Crystal product: pharmaceutical grade sodium chloride — high value if purity specifications met

Mining — Acid Mine Drainage

Acid mine drainage (AMD) from sulphide ore oxidation contains sulphuric acid, high sulphate, iron, and heavy metals at TDS 2,000–30,000 mg/L. ZLD prevents discharge to sensitive catchments and recovers water for reuse in the process plant — critical for mines in arid locations. See our AMD treatment page.

  • Pre-treatment: lime neutralisation → heavy metal precipitation → lamella clarifier → multimedia filter
  • Membrane stage: high-pressure RO (20–35 bar for high-sulphate feeds); antiscalant essential
  • Crystal product: gypsum (CaSO&sub4;·2H&sub2;O) — potential sale to cement or wallboard industry
  • Water recovery: 85–92% of mine dewatering flow returned to process

Indicative ZLD Capital Cost Ranges

For budgetary purposes only — actual costs depend heavily on feed composition, required solid purity, and integration with existing infrastructure.

Flow / ScalePre-treatment + ROEvaporation (MVR)CrystalliserTotal ZLD Train
100 m³/day
500 m³/day
2,000 m³/day

Figures are indicative AACE Class 5 estimates (±50%). A full feasibility study including feed characterisation, technology selection, and mass balance is required before project commitment. Contact us to begin the process.

Related Pages

ZLD System Overview

Full ZLD system architecture from pre-treatment through crystallisation.

ZLD Overview

ZLD Evaporation

MVR and MEE brine concentration systems and scaling control.

Evaporation

ZLD Crystallisation

FC and DTB crystallisers for solid salt recovery.

Crystallisation

Acid Mine Drainage

AMD pre-treatment and ZLD for mining operations.

AMD Treatment

Discuss Your Project

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Industries We Serve

Our expertise spans multiple industries with sector-specific water treatment solutions.