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Physico-Chemical Treatment Systems

Advanced dissolved air flotation, chemical dosing, and polymer preparation systems for effective removal of suspended solids, fats, oils, and contaminants.

How Physico-Chemical Treatment Works

A proven multi-stage process combining chemical conditioning with physical solid-liquid separation

Physico-chemical conditioning and treatment combines chemical reactions (coagulation and flocculation) with physical solid-liquid separation processes (flotation or sedimentation) to remove suspended solids, colloidal particles, fats, oils, and other contaminants from wastewater.

1

Chemical Conditioning

Wastewater mixed with coagulants and flocculants

2

Flocculation

Gentle mixing creates larger floc particles

3

Air Saturation

Water saturated with air under pressure

4

Micro-Bubble Release

Bubbles attach to contaminant particles

5

Flotation & Separation

Sludge rises to surface for removal

1

Select a Process Step

Click any process step above to view detailed engineering parameters and design considerations.

Physico-Chemical Engineering Guide

Technology selection matrix (DAF vs Lamella vs Clarifier), typical design parameters, coagulation chemistry, G-values, and process integration diagrams. Read the full guide →

Coagulation & Flocculation Foundations

From colloidal stability to the Camp number — the physical chemistry behind every coagulant dose

Colloidal Stability & Zeta Potential

Suspended colloids (clay, organic matter, oil droplets, bacterial cells) carry a net negative surface charge. The resulting electrical double layer creates a repulsion that keeps particles dispersed indefinitely — raw water zeta potential typically sits at −15 to −30 mV. DLVO theory describes the net interaction as the sum of attractive London–van der Waals forces and repulsive electrostatic forces; coagulation reduces ζ toward −5 to +5 mV, collapsing the repulsion barrier and letting particles aggregate on first collision.

Coagulant Hydrolysis & Optimum pH

Metal salts hydrolyse to form polynuclear hydroxide species that neutralise charge and sweep colloids into a precipitate:

  • Alum [Al2(SO4)3·14H2O]: optimum pH 6.0–7.5; minimum solubility of Al(OH)3 at pH 6.3. Typical dose 20–150 mg/L.
  • Ferric chloride [FeCl3]: optimum pH 4.5–6.0 or >8.0; broader operating window than alum. Dose 30–200 mg/L.
  • PACl (polyaluminium chloride): pH 5.5–9.0, lower acid consumption, 30–60% less sludge than alum at equivalent removal.
  • Cationic polymer (alone): pH 4–10; doses 0.5–5 mg/L — charge neutralisation only, no sweep floc.

Velocity Gradient G & Camp Number Gt

Mixing intensity is quantified by the root-mean-square velocity gradient G = (P / μV)1/2 (units: s−1). The dimensionless Camp number Gt is the integrated product of G and residence time and controls the floc-collision yield.

StageG (s−1)t (min)Gt
Rapid mix (coagulation)500–1,5000.5–13×104–1×105
Flocculation, stage 160–805–103–5×104
Flocculation, stage 230–505–102–3×104
Flocculation, stage 310–255–101–1.5×104

Tapering G downwards through the flocculation train prevents shear-breakage of mature flocs while still driving orthokinetic collisions.

Smoluchowski Flocculation Kinetics

The rate of particle aggregation under fluid shear (orthokinetic regime) is dN/dt = −(4/π)·α·G·φ·N, where N is the particle number concentration, α the collision efficiency (post-coagulation: 0.3–1.0), G the velocity gradient and φ the floc volume fraction. Integrating gives N/N0 = exp(−(4/π)·α·G·φ·t) — particle count drops exponentially with Gt, which is why the Camp number is the master design variable. Floc size grows until the shear-breakage limit dmax ∝ G−1/2, typically 0.5–3 mm at G = 20–80 s−1.

Jar test → design dose. The optimum coagulant dose, polymer type and pH for a real wastewater cannot be calculated from first principles — they must be measured with a six-paddle jar test (G = 100 s−1, 1 min → G = 30 s−1, 15 min → 30 min settle). Residual turbidity and zeta-potential vs dose define the operating curve; we use the inflection point at ζ = −5 to +5 mV as the design dose, then validate at pilot scale.

Physico-Chemical Treatment Systems

Complete range of equipment for chemical conditioning and treatment applications

Dissolved Air Flotation (DAF) Systems

Effective removal of suspended solids, fats, oils, and grease

Dissolved Air Flotation (DAF) is a proven physico-chemical conditioning and treatment process that removes suspended solids, fats, oils, and other contaminants by introducing micro-bubbles that attach to particles and float them to the surface for removal. Design is governed by four interdependent parameters: hydraulic loading rate (5–15 m/h), air-to-solids ratio (0.01–0.05 kg/kg), saturator pressure (400–600 kPa), and recycle ratio (8–25%).

90%+
TSS Removal
95%+
Fats & Oils
30+
Years Proven
500
m³/h Max

Maximum Efficiency

Removes up to 95% of fats, oils, and suspended solids

Space-Efficient Design

Smaller footprint than conventional sedimentation

Fast Startup

Quick response to flow and load variations

Low Sludge Volume

Concentrated sludge with higher solids content

View DAF System Details

Lamella Flotator

Compact flotation with inclined plate separation

Flotation system with internal partition walls reducing unit size without losing efficiency. Removable stainless steel lamella packs allow easy cleaning without cranes. Plate spacing of 50–120 mm and angle of 55–60° provide equivalent settling area = plan area × (cos θ / sin θ) × number of plates.

Space-Efficient Design

Internal partition walls reduce footprint

Easy Maintenance

Removable lamella packs enable easy cleaning

Efficiency Gains

Reduced installation and maintenance requirements

View Full Specifications

Chemical Dosing Systems

Precise coagulant and pH adjustment dosing

Automated chemical dosing systems for coagulants, pH adjustment, and other treatment chemicals. Systems include diaphragm or peristaltic pumps (10:1 turndown), calibration columns, pulsation dampers, back-pressure valves, and injection quills in SS316 or Hastelloy. Full SCADA integration with flow-paced dosing and residual feedback control.

Precise Dosing

Flow-proportional dosing with real-time adjustment

Multiple Chemicals

Handle coagulants, flocculants, pH adjusters

SCADA Integration

Full automation and remote monitoring

View Chemical Dosing Details

Polymer Preparation Stations

Automated polyelectrolyte preparation and dosing

Our polymer stations ensure precise preparation and dosing of polyelectrolyte solutions for optimal flocculation. Powder systems require 2–5 minute wetting and 30–60 minute maturation; emulsion systems activate in 10–20 minutes. Concentration ranges: 0.1–0.5% for powder, 0.2–1.0% for emulsion. Tank materials: PE or SS316.

Multiple Configurations

Flow-through, batch, pendulum, and compact systems

Consistent Quality

Automated preparation ensures optimal activation

Cost Efficient

Minimises polymer consumption

View Polymer Station Details

Detailed Information

Explore our comprehensive guides to physico-chemical conditioning and treatment

Process Vessels & Tanks

Physico-chemical conditioning and treatment requires specialised mixing, reaction and separation tanks.

Flash Mix Tanks

Rapid mixing vessels for coagulant dispersion.

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Flocculation Tanks

Gentle mixing tanks for floc growth and conditioning.

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Settling Tanks

Sedimentation tanks for solids separation and sludge collection.

View Settling Tanks

Related Treatment Processes

Explore the connected unit processes and their engineering guides

Sediment Removal

Grit, sand, silt and colloidal solids removal across the full particle-size spectrum, with Stokes-law settling theory and discharge compliance.

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pH Adjustment

Acid-base chemistry, buffer capacity and titration-curve-led neutralisation with CO2 and acid/alkali dosing systems.

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Coagulation & Flocculation

The physical chemistry of charge neutralisation, the Camp number and floc formation behind every coagulant dose.

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Need a Custom Physico-Chemical Treatment Solution?

Our engineering team can design a system tailored to your specific wastewater characteristics and treatment requirements. Contact us for a free consultation.

API Separators — Engineering Deep-Dive

Stokes’-law sizing, API Publication 421 design methodology, rectangular API / CPI / TPI configurations and refinery-train integration.

Industries We Serve

Our expertise spans multiple industries with sector-specific water treatment solutions.