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Multimedia Filtration for Iron & Manganese Removal

Worked design example: Birm catalytic pre-stage and triple-media pressure filters treating borehole water with elevated iron (2.1 mg/L) and manganese (0.18 mg/L) for food-grade process water. 18 m³/hr continuous duty, cascade aeration, potassium permanganate oxidation, automatic backwash.

Borehole & Groundwater Treatment

Treating a borehole or groundwater supply? See our full approach — aeration and catalytic multimedia filtration for iron and manganese, ultrafiltration for SDI and RO pre-treatment, and disinfection for potable supply — with example arrangements by application.

Borehole Treatment

Application Context — Borehole Water to Food Production

Project Overview

Borehole SourceIron RemovalManganese RemovalFood-Grade Water18 m³/hr

A baked-goods manufacturer draws process water exclusively from a private borehole at 18 m³/hr. A water analysis commissioned following product quality complaints revealed iron at 2.1 mg/L and manganese at 0.18 mg/L — ten times and three times the EU Drinking Water Directive limits respectively. Raw turbidity is 3.2 NTU. Iron staining is occurring on internal pipe surfaces and product contact equipment; manganese produces a metallic off-taste in product. The site’s trade association technical audit has flagged the raw supply as non-compliant with the food safety plan. A dedicated iron and manganese removal system is required upstream of the production water storage tank, targeting outlet concentrations of < 0.05 mg/L Fe and < 0.02 mg/L Mn.

Raw Water Quality and Treatment Targets

Design Flow Rate
18 m³/hr
Iron (Inlet)
2.1 mg/L Fe
Manganese (Inlet)
0.18 mg/L Mn
Turbidity (Inlet)
3.2 NTU
pH
7.1
Target Iron (Outlet)
< 0.05 mg/L
Target Manganese
< 0.02 mg/L
Target Turbidity
< 0.5 NTU

DWD limits for context: The EU Drinking Water Directive (2020/2184) sets Fe at 0.2 mg/L and Mn at 0.05 mg/L as parametric values. For food production, internal food safety plans typically specify tighter limits at the point of use. This design targets 0.05 mg/L Fe and 0.02 mg/L Mn to provide a working margin against analytical variation and any concentration from dead-legs within the facility distribution system.

When Is a Greensand Pre-Stage Required?

Not every borehole requires greensand filtration. The appropriate treatment train depends on iron and manganese concentrations and the outlet quality target:

Raw IronRaw ManganeseRecommended Treatment
< 0.3 mg/L< 0.05 mg/LMultimedia filter alone (in-bed contact oxidation with dissolved oxygen)
0.3–1.0 mg/L< 0.05 mg/LCascade aeration + multimedia filter
> 1.0 mg/L< 0.05 mg/LAeration + greensand or Birm pre-stage + multimedia polishing filter
Any0.05–0.2 mg/LChemical oxidation (KMnO₄) + greensand/Birm + multimedia filter
> 2.0 mg/L> 0.1 mg/LFull iron/Mn plant: cascade aeration, KMnO₄ dosing, greensand, multimedia — this application
Why multimedia alone is insufficient at these concentrations: Multimedia filters can retain oxidised Fe(OH)₃ floc at low iron levels (< 0.3 mg/L) where in-bed contact oxidation is sufficient. At 2.1 mg/L Fe, the precipitate loading would foul a standard multimedia bed within hours. Manganese at 0.18 mg/L requires catalytic media to achieve reliable sub-0.02 mg/L outlet — dissolved oxygen alone in a sand bed does not oxidise Mn²⁺ fast enough at these concentrations.

Iron and Manganese Removal Process Train

1

Borehole Supply

Borehole pump delivers water at 18 m³/hr. At pH 7.1 the iron is predominantly in the soluble Fe²⁺ form — clear and colourless at this point. Manganese is fully dissolved as Mn²⁺. Both are invisible in solution; discolouration only develops after oxidation and precipitation downstream.

2

Cascade Aeration

Water cascades over a packed aeration tower or tray cascade, introducing atmospheric oxygen. Aeration oxidises Fe²⁺ to Fe³⁺ (rust-coloured Fe(OH)₃ precipitate): 4Fe²⁺ + O₂ + 10H₂O → 4Fe(OH)₃ + 8H⁺. CO₂ stripping during aeration raises pH from 7.1 to approximately 7.4–7.6, improving the kinetics for downstream manganese oxidation. Aeration alone cannot achieve the Mn outlet target at this concentration.

3

Potassium Permanganate Dosing

KMnO₄ solution is dosed by a peristaltic pump at approximately 1.9 g per gram of Mn²⁺ (stoichiometric requirement). At pH ≥ 7.0, KMnO₄ rapidly and reliably oxidises Mn²⁺ to MnO₂ precipitate, independent of dissolved oxygen availability. A flow-paced dosing controller maintains the correct dose rate across varying borehole flows; an online manganese analyser on the treated water outlet verifies product quality and triggers a high-level alarm if Mn exceeds 75% of the target limit.

4

Birm Catalytic Pressure Filter

A GRP pressure vessel charged with Birm® catalytic media retains the Fe(OH)₃ and MnO₂ precipitates formed upstream. Birm also catalyses continued in-bed oxidation of residual Mn²⁺ using dissolved oxygen — no chemical regenerant is needed; backwash with clean water restores the bed. Backwash triggered at 0.4 bar differential pressure or a 48-hour timer. Outlet from this stage: Fe < 0.1 mg/L, Mn < 0.05 mg/L.

5

Triple-Media Polishing Filter

A second GRP pressure vessel charged with anthracite–sand–garnet removes residual turbidity and any fine Fe/Mn fines that escape the Birm stage. Turbidity is reduced from approximately 1–2 NTU to < 0.5 NTU. The media bed also provides a guard against any KMnO₄ overdose events: residual permanganate adsorbs onto the anthracite, preventing pink colouration in the product water. Outlet: Fe < 0.05 mg/L, Mn < 0.02 mg/L, turbidity < 0.5 NTU.

6

Production Water Storage

Treated water enters the existing 50 m³ production water storage tank, compliant with the EU Drinking Water Directive and the site food safety plan. Continuous inline turbidity and iron monitoring on the treated water delivery line provides early warning of any exceedances before water reaches the production process or storage tank.

Greensand and Catalytic Media Comparison

The choice of iron/manganese filtration media directly affects maintenance demands, chemical storage requirements, achievable flow rates, and long-term running costs:

MediaMechanismRegenerantMax SLRMn RemovalNotes
Manganese Greensand (glauconite)Adsorption + catalysisDilute KMnO₄ solution (periodic)5–8 m/hExcellentTraditional choice; requires chemical storage
Birm®Catalysis (DO-dependent)None8–12 m/hGood (pH ≥ 6.8)Recommended — simplest operation, no chemical store
Pyrolox (MnO₂)CatalysisNone3–5 m/hExcellentVery dense; suits low flow rates; highest capacity
MTM (Micro-Thane-Media)CatalysisNone10–15 m/hExcellentPremium; high capacity; smallest vessel footprint
Filox-R (72% MnO₂)CatalysisNone5–7 m/hExcellentHigh MnO₂ content; handles high Fe + Mn simultaneously

Recommended for this application — Birm®: At pH 7.1–7.5 post-aeration and with substantial dissolved oxygen available from the cascade aeration stage, Birm provides reliable Mn oxidation without any chemical regeneration. Designed conservative SLR of 8 m/h gives a required vessel area of 2.25 m² (approximately 1,700 mm vessel diameter). No KMnO₄ chemical storage or periodic regeneration is required; only clean backwash water. If a future analysis reveals Mn spiking above 0.3 mg/L, upstream KMnO₄ dosing can be added without replacing the Birm media.

Two-Stage Vessel Sizing at 18 m³/hr

StageMediaSLRRequired AreaVessel DiameterS/S Height
Stage 1 — Iron & Manganese RemovalBirm® catalytic media8 m/h2.25 m²1,700 mm~2,200 mm
Stage 2 — Multimedia PolishingAnthracite / Sand / Garnet12 m/h1.5 m²1,400 mm~2,000 mm

Footprint estimate: Both GRP vessels side by side require approximately 3.5 m width × 1.75 m depth, plus service access. The cascade aeration tower (typically 0.8–1.2 m diameter × 2.5–3.0 m height) can be sited outdoors adjacent to the filtration building or inside if headroom permits. The KMnO₄ dosing skid (including day tank, dosing pump, and containment bund) adds approximately 0.8 m × 0.8 m. Total installation footprint including pipework, dosing skid, and service clearances: approximately 5.5 m × 2.5 m.

Design Your Iron and Manganese Removal System

Our process engineers will review your borehole water analysis, flow rate targets, and product quality requirements to size the aeration stage, select the optimum catalytic media, and design the polishing multimedia filter and backwash sequence.

Explore All Multimedia Pre-RO Filter Options

Parent Overview

Technology selection, SDI targets, hydraulic design, and backwash sizing for multimedia pre-RO filtration.

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Triple-Media Filters

Anthracite / sand / garnet for the best SDI reduction — the standard pre-RO media configuration for most applications.

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Duplex Systems

Parallel vessel pairs for uninterrupted 24/7 operation where backwash must not cut the downstream supply.

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Boiler Feed Example

Borehole to duplex triple-media to RO to steam boiler at 24 m³/hr — detailed vessel sizing and control design.

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Iron & Manganese Example

Greensand pre-stage and triple-media treating borehole water with elevated Fe/Mn for food-grade process water.

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Cooling Tower Example

Multimedia filtration for cooling tower make-up water at 45 m³/hr with L8 turbidity compliance.

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Pharmaceutical Example

GMP-compliant multimedia pre-treatment for purified water systems. 316L SS, sanitisable, validated.

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Industries We Serve

Our expertise spans multiple industries with sector-specific water treatment solutions.