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Refinery Wastewater Treatment

Engineered multi-stage treatment systems for petroleum refinery effluents, addressing oil removal, phenol reduction, sulphide treatment, and COD compliance. From API separation and DAF flotation to biological polishing, we design integrated solutions that meet EPA, EU BREF, and local discharge standards while enabling water reuse.

Industry Overview

Complex Wastewater from Petroleum Refining

Petroleum refineries generate complex wastewater streams containing free and emulsified oil, phenols, sulphides, ammonia, and high concentrations of organic compounds. Our integrated treatment solutions address each contaminant class through proven processes, ensuring compliance with increasingly stringent discharge regulations while maximising water reuse opportunities. Oil separation, sour-water stripping, biological treatment and tertiary polishing are integrated into a single resilient train. Reynolds & Bauhm tune each stage to the refinery’s crude slate and consent so it meets tightening limits while maximising reuse.

Oil & Grease Removal

Multi-stage oil separation achieving <15 mg/L O&G through API separators, DAF, and coalescing media for discharge compliance.

Phenol Treatment

Specialised biological and chemical processes for phenol removal, achieving <0.5 mg/L to meet strict environmental limits.

COD Reduction

Advanced advanced biological treatment systems achieving 90%+ COD removal through MBBR, SBR, or activated sludge processes.

Water Reuse

Polishing treatment enabling water recycling for cooling towers, boiler feed, and process applications reducing freshwater demand.

Sludge Management

Integrated dewatering of API separator bottoms, DAF float, and biological sludge to reduce disposal requirements by 60-80%.

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Typical Effluent Characteristics

Refinery Wastewater Parameters & Treatment Targets

ParameterTypical Influent RangeTreatment TargetPrimary Technology
Oil & Grease50 – 500 mg/L< 15 mg/L (discharge) / < 5 mg/L (reuse)API + DAF
COD500 – 2,500 mg/L< 125 mg/LMBBR / SBR
Phenols10 – 200 mg/L< 0.5 mg/LBiological Treatment
Sulphides (as SΒ²-)5 – 150 mg/L< 1 mg/LSWS + Biological
Ammonia-N20 – 300 mg/L< 10 mg/LSteam Stripping + Nitrification
TSS50 – 400 mg/L< 30 mg/LLAMELLA + Filtration
BOD5200 – 1,500 mg/L< 25 mg/LBiological Oxidation
Temperature25 – 60 Β°C< 40 Β°C (biological)Equalization + Cooling

Values are representative of combined refinery effluents. Actual performance depends on crude slate, process configuration, and local regulatory requirements.

Global Compliance Standards

Meeting Refinery Discharge Requirements Worldwide

US EPA

Compliance with EPA Effluent Guidelines for Petroleum Refining (40 CFR 419) covering Best Available Technology (BAT) limits for oil, phenol, sulphide, TSS, and ammonia.

EU Refinery BREF

Design and operation aligned with the EU Industrial Emissions Directive and Best Available Techniques Reference Document for the Refining of Mineral Oil and Gas.

IMO MEPC

Marine discharge compliance for coastal and offshore refinery operations in accordance with MARPOL Annex I and MEPC guidelines.

Local Permits

Tailored designs to meet site-specific discharge permits, Water Framework Directive standards, and regional environmental quality standards.

Applications

Refinery Wastewater Sources

Process Area Runoff

Treatment of oily wastewater from crude and product storage areas, process units, and equipment drainage systems.

Explore Process Runoff

Desalter Effluent

High-salinity wastewater from crude oil desalting containing oil, solids, and dissolved salts requiring specialised treatment.

Explore Desalter

Sour Water Stripper

Treatment of stripped sour water containing ammonia, phenols, and reduced sulphur compounds from amine and sulphur recovery units.

Explore Sour Water Stripper

Tank Bottoms

High-solids wastewater from tank cleaning and bottoms removal with concentrated oil and sludge content.

Explore Tank Bottoms

Coking Operations

Treatment of wastewater from delayed coking and fluid coking units with high phenol and COD concentrations.

Explore Coking

Utilities Wastewater

Treatment of blowdown and drainage from cooling towers, boilers, and utility systems throughout the refinery.

Explore Utilities

Treatment Process

Integrated Refinery Wastewater Treatment

1

Equalization

Flow and load balancing to handle variable refinery wastewater characteristics and shock loads.

2

Oil Separation

API separators and DAF remove free and emulsified oil from wastewater streams.

3

Clarification

LAMELLA separators remove precipitated solids and chemical floc with high-rate settling.

4

Biological Treatment

MBBR or SBR systems remove dissolved organics, phenols, and reduce COD/BOD.

5

Final Polishing

Self-cleaning filters provide final suspended solids removal before discharge.

Recommended Equipment

Products for Refinery Wastewater

DAF Flotation Systems

High-efficiency oil and solids removal through microbubble flotation for refinery wastewater.

Benefit: 95%+ oil removal

API Separators

Gravity oil-water separation for free oil removal upstream of secondary treatment processes.

Benefit: Low operating requirement

MBBR Systems

Moving bed biofilm reactors for high-rate COD and phenol removal in compact footprint.

Benefit: 90%+ COD removal

LAMELLA Clarifiers

High-rate solids separation for primary and tertiary clarification in minimal space.

Benefit: 70% smaller footprint

Sludge Dewatering

Screw presses and centrifuges for refinery sludge dewatering to minimise disposal requirements.

Benefit: 60-80% efficiency improvement

Self-Cleaning Filters

Automatic backwash filtration for final polishing and protection of downstream equipment.

Benefit: Continuous operation

Key Benefits

Why Choose Reynolds & Bauhm

Meet stringent refinery discharge standards worldwide
Handle variable wastewater composition and flow
Recover saleable oil from wastewater streams
ATEX-certified equipment for hazardous areas
Enable water reuse reducing freshwater requirements
Automated operation minimising staffing needs
Robust construction for 24/7 operation
Integration with existing refinery DCS systems

Refinery Treatment Processes

Deep-Dive into Key Treatment Steps

Oil Separation

Multi-stage oil removal using API separators, DAF, and coalescing media to achieve discharge compliance.

Explore Oil Separation

Biological Treatment

MBBR and SBR systems engineered for phenol removal and high COD reduction in refinery effluents.

Explore Biological Treatment

Sour Water Treatment

Specialised handling of sour water stripper bottoms and desalter effluent with high salinity and sulphides.

Explore Sour Water

Sludge Management

Dewatering and oil recovery from API separator bottoms, DAF float, and biological waste sludge.

Explore Sludge Management

Water Reuse

Polishing systems converting treated effluent into cooling tower makeup and boiler feed pre-treatment.

Explore Water Reuse

ATEX Compliance

Explosion-proof equipment and controls certified for safe operation in refinery hazardous zones.

Explore ATEX

Related Applications

Explore Other Oil & Gas Solutions

Produced Water Treatment

Treatment of formation water from oil and gas wells for discharge or reinjection.

Explore Produced Water

Petrochemical Plants

Specialised treatment for petrochemical manufacturing wastewater streams.

Explore Petrochemical

Downstream Operations

Comprehensive treatment for downstream oil and gas processing facilities.

Explore Downstream

Midstream Operations

Wastewater treatment for pipelines, terminals, and storage facilities.

Explore Midstream

Related Pages

Chemical Atex

Chemical industry wastewater treatment for atex-certified equipment.

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Global Standards Reference

Directory of international wastewater treatment regulations and equipment compliance standards Organised by country and region.

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Oil Water Separation

Oil and gas wastewater treatment for oil-water separation systems.

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Oilgas Atex

ATEX-certified wastewater treatment equipment for explosive atmospheres in oil, gas and petrochemical facilities.

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Oilgas Downstream

Refinery wastewater treatment including API separators, DAF, advanced biological treatment and polishing for strict discharge.

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Oilgas Drilling

Treat drilling muds, cuttings wash water and site runoff.

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Refinery Wastewater Streams β€” Engineering Map

Each refinery effluent stream demands a tailored treatment path. Mixing streams without pre-segregation almost always raises Capital expenditure and Operating expenditure.

Stripped Sour Water

Post sour-water stripper (SWS) effluent: 5–30 mg/L NH₃, 1–5 mg/L Hβ‚‚S, phenols 10–100 mg/L. Biological treatment after equalisation; PAC or ozonation for phenol polishing.

Desalter Effluent

Crude desalter water: high TSS (300–2,000 mg/L), salts (5,000–50,000 mg/L TDS), trace metals, mercaptans. API separation β†’ IGF/DAF β†’ biological. Salt content limits reuse.

Coker / FCC Effluent

High COD (1,500–5,000 mg/L), phenols, cyanide, sulphides. Pre-treat with chemical oxidation or steam stripping before biological. Often the rate-limiting stream for the plant biology.

Process Area Runoff

Stormwater commingled with oil-spill drips. Three-stage API + DAF + sand filter. Sized for design rainfall event with overflow to off-spec holding pond.

Utility / Cooling Tower Blowdown

Side-stream filtration, sometimes lime softening, conditioning for reuse. Discharge stream is high TDS, low BOD β€” can run separately to reduce biological load.

Tank Bottoms & Sludge

Oily sludge with 20–60% oil content. Three-phase decanter or centrifuge for oil recovery; solids to disposal or co-processing. Aqueous phase recycled to head of works.

StreamTypical COD (mg/L)Key contaminantPrimary treatment
Stripped sour water200–800Phenols, residual NH₃Bio + PAC/GAC polish
Desalter500–2,500Oil, TSS, saltsAPI + DAF + bio
Coker / FCC1,500–5,000Phenols, cyanidePre-oxidation + bio
Process runoff100–500 (event)Free oil, TSSAPI + DAF + filter
Utility blowdown50–200TDS, scale inhibitorsSide-stream filter
Tank bottoms5,000–30,000Oily sludgeDecanter centrifuge

API Separators β€” Engineering Deep-Dive

Stokes’-law sizing, API Publication 421 design methodology, rectangular API / CPI / TPI configurations and refinery-train integration.

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Industries We Serve

Our expertise spans multiple industries with sector-specific water treatment solutions.