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Industry Overview

Biological Removal of Refinery Organics

After oil separation, refinery wastewater still contains high concentrations of dissolved organics, phenols, sulphides, and ammonia that must be removed before discharge. Our advanced biological treatment systems use specialised microbial communities adapted to petroleum hydrocarbons, achieving 90%+ COD removal and <0.5 mg/L phenol concentrations even under variable loading conditions. Reynolds & Bauhm design acclimated activated-sludge, MBBR and MBR systems sized for refinery shock loads and toxic-compound resilience. Robust aeration, nutrient dosing and clarification deliver consistent COD, phenol and ammonia removal even under upset conditions.

High COD Removal

MBBR and SBR systems achieve 90%+ COD reduction from typical refinery influent concentrations of 500-2,000 mg/L.

Phenol Degradation

Specialised phenol-acclimated biofilms remove toxic phenolic compounds to <0.5 mg/L meeting strict environmental limits.

Sulphide Oxidation

Biological sulphide oxidation converts reduced sulphur compounds to elemental sulphur or sulphate preventing toxicity and odours.

Shock Load Resilience

Moving bed biofilm reactors tolerate phenol and hydrocarbon shock loads better than conventional activated sludge.

Applications

Refinery Biological Treatment Sources

Sour Water Stripper Bottoms

Biological treatment of stripped sour water containing ammonia, phenols, and reduced sulphur compounds after steam stripping.

Coking Operations

Treatment of wastewater from delayed coking and fluid coking units with high phenol and COD concentrations.

Catalytic Cracking

Biological removal of organics from FCC unit wastewater containing oil, phenols, and sulphides.

Hydroprocessing Units

Treatment of effluent from hydrotreating and hydrocracking operations with high nitrogen and sulphur content.

Process Area Runoff

Biological polishing of combined refinery wastewater after primary oil separation and clarification.

Utilities Wastewater

Treatment of blowdown and drainage from cooling towers, boilers, and utility systems throughout the refinery.

Treatment Process

Integrated Biological Treatment Process

1

Pre-Treatment

Oil separation and clarification protect biological systems from oil toxicity and solids accumulation.

2

Equalization

Equalization tanks dampen flow and concentration variations to maintain stable biological conditions.

3

Biological Reactor

MBBR or SBR systems remove dissolved organics, phenols, and reduce COD/BOD through biofilm oxidation.

4

Secondary Clarification

LAMELLA separators settle biological sludge for recycle or wasting, producing clear effluent.

5

Final Polishing

Self-cleaning filters remove residual biomass and solids before discharge or reuse.

Recommended Equipment

Products for Refinery Biological Treatment

MBBR Systems

Moving bed biofilm reactors for high-rate COD and phenol removal in compact footprint.

Benefit: 90%+ COD removal

SBR Systems

Sequencing batch reactors providing batch advanced biological treatment with built-in settling phases.

Benefit: Flexible operation

Fine Bubble Aeration

High-efficiency diffused aeration systems delivering oxygen for biological oxidation.

Benefit: Energy efficient

LAMELLA Clarifiers

High-rate solids separation for secondary clarification and sludge recycle.

Benefit: 70% smaller footprint

Sludge Dewatering

Screw presses and centrifuges for biological sludge dewatering to minimise disposal requirements.

Benefit: 60-80% efficiency improvement

Self-Cleaning Filters

Automatic backwash filtration for final suspended solids removal before discharge.

Benefit: Continuous operation

Key Benefits

Why Choose Reynolds & Bauhm

Achieve 90%+ COD and BOD removal
Reduce phenol to <0.5 mg/L discharge limits
Handle toxic and variable refinery loads
Compact MBBR footprint for retrofits
Resilient biofilms resist shock loads
Automated SBR sequencing reduces labour
Integrated nutrient dosing control
Proven refinery acclimation protocols

Related Refinery Processes

Explore Other Refinery Treatment Steps

Refinery Overview

Comprehensive multi-stage treatment for petroleum refinery effluents.

Explore Oilgas Refinery

Oil Separation

API separators and DAF systems for refinery oil and grease removal.

Explore Oil Separation

Sour Water Treatment

Specialised handling of sour water stripper bottoms and desalter effluent.

Explore Sour Water

Sludge Management

Dewatering and oil recovery from refinery sludge streams.

Explore Sludge Management

Water Reuse

Polishing systems for cooling tower makeup and boiler feed pre-treatment.

Explore Water Reuse

ATEX Compliance

Equipment engineered for explosive atmospheres with ATEX certification.

Explore ATEX

Related Pages

Chemical Atex

Chemical industry wastewater treatment for atex-certified equipment.

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Global Standards Reference

Directory of international wastewater treatment regulations and equipment compliance standards Organised by country and region.

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Oil Water Separation

Oil and gas wastewater treatment for oil-water separation systems.

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Oilgas Atex

ATEX-certified wastewater treatment equipment for explosive atmospheres in oil, gas and petrochemical facilities.

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Oilgas Downstream

Refinery wastewater treatment including API separators, DAF, advanced biological treatment and polishing for strict discharge.

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Oilgas Drilling

Treat drilling muds, cuttings wash water and site runoff.

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Refinery Biological Treatment — Design Parameters

Refinery biology runs hot, salty and toxic. Standard municipal kinetics do not apply.

Operating Temperature

Influent typically 30–45°C from stripper/cooling water. Mesophilic biology design at 35–38°C. Cooling tower may be needed to prevent overheating in summer.

Inhibition & Toxicity

Phenols toxic above 100–200 mg/L; sulphide above 50 mg/L; ammonia above 1,500 mg/L. Use acclimated biomass; provide chemical pre-treatment buffer.

F/M Ratio

0.15–0.30 kg BOD/kg MLVSS·d for refinery streams (lower than municipal). MLSS 3,000–5,000 mg/L. SRT 15–25 days to enable nitrification.

MBBR vs CAS

MBBR preferred for retrofit: tolerates shock load, accommodates seasonal variability. CAS preferred for greenfield where space is available.

Phenol Bioremediation

Specialised phenol-acclimated biomass; SRT ≥20 days; multi-stage to handle shock loads. Polish with GAC or AOP for <1 mg/L residual.

Nitrification

Inhibited by phenol >5 mg/L. Separate nitrification basin downstream of carbon removal. DO >2.5 mg/L, pH 7.0–8.5, alkalinity supplement.

ParameterMunicipal (reference)Refinery biological
F/M (kg BOD/kg MLVSS·d)0.20–0.500.10–0.30
MLSS (mg/L)2,500–4,0003,000–5,000
HRT (h)4–812–36
SRT (d)5–1515–25
DO (mg/L)1.5–2.52.0–3.5
Phenol max (mg/L)n/a<100 with acclimation
Effluent BOD (mg/L)<15<25

API Separators — Engineering Deep-Dive

Stokes’-law sizing, API Publication 421 design methodology, rectangular API / CPI / TPI configurations and refinery-train integration.

Need Refinery Biological Treatment?

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Industries We Serve

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